Selective chemical modification of DNA with alkoxy- and benzyloxyamines

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Selective chemical modification of DNA with alkoxy- and benzyloxyamines.

A new method for the selective chemical modification of DNA at cytosine nucleobases using alkoxy- and benzyloxyamines is presented. It is shown that in particular benzyloxyamines are effective DNA modifying agents, giving rise to almost exclusive formation of the mono addition products. By using a bifunctional derivative, that is, p-azidobenzyloxyamine hydrochloride, an azide moiety, which is a...

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ژورنال

عنوان ژورنال: Organic & Biomolecular Chemistry

سال: 2015

ISSN: 1477-0520,1477-0539

DOI: 10.1039/c5ob00595g